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Ligands that are more sterically demanding in the vicinity of the metal center tend to limit the ability of other ligands to bind than those which bind through a small extended group

Qi, M., Fadool, D

Wei L, Zhang J, Wei S, Wang C, Deng Y, Hu D, Liu H, Gong W, Pan Y, Liao W (2022) Nitric oxide alleviates salt stress through protein S-nitrosylation and transcriptional regulation in tomato seedlings

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since this modification blocks formation of the iminium species but not the imoquinone, iminium formation is inferred to be the main cause of toxicity (Kalgutkar et al., 2002)

Never attempt to compensate for potentially reduced medication potency by increasing your dose without medical supervision